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印度尼西亚沿海水域选定地点沉积物中防污生物杀灭剂和全氟烷基化合物的分布。

Distribution of antifouling biocides and perfluoroalkyl compounds in sediments from selected locations in Indonesian coastal waters.

机构信息

Department of Human Sciences, Kobe College, Nishinomiya, Hyogo, Japan.

出版信息

Arch Environ Contam Toxicol. 2012 Jul;63(1):13-21. doi: 10.1007/s00244-011-9747-y. Epub 2012 May 9.

Abstract

Coastal marine environments are considered to be the most sensitive areas for the accumulation of organotin (OT) compounds and other emerging new pollutants, such as perfluoroalkyl compounds. Contamination by these compounds is a matter of great concern due to their accumulation and possible negative impact on the coastal environment and organisms. The concentrations of tributyltin (TBT) compounds were greater in Indonesia, i.e., on the order of Bitung > Manado > Jakarta Bay > Gangga Island, and TBT in sediment from Bitung and Manado was the dominant species among butyltin (BT) compounds. Sea Nine 211, diuron, and irgarol 1051 were detected among alternative biocides in Bitung, Manado, and Gangga Island and irgarol 1051 was detected in Jakarta Bay. Perfluorooctanoic acid (PFOA) and perfluorosulfonic acid (PFOS) in Jakarta Bay were detected at 0.25 to 6.1 μg kg(-1) dry weight (dw) and 0.58 to 3.7 μg kg(-1) dw, respectively, and the concentrations of PFOS at most sampling sites were greater than those of PFOA. Thus, coastal waters from Indonesia have already been contaminated by antifouling biocides and perfluoroalkyl compounds.

摘要

沿海海洋环境被认为是有机锡(OT)化合物和其他新兴新型污染物(如全氟烷基化合物)积累的最敏感区域。由于这些化合物的积累及其对沿海环境和生物可能产生的负面影响,它们的污染是一个非常令人关注的问题。印度尼西亚的三丁基锡(TBT)化合物浓度较高,即比通>万鸦老>雅加达湾>甘加岛,比通和万鸦老沉积物中的 TBT 是丁基锡(BT)化合物中的主要物质。在比通、万鸦老和甘加岛的替代杀生物剂中检测到 Sea Nine 211、敌草隆和 Irgarol 1051,在雅加达湾检测到 Irgarol 1051。雅加达湾的全氟辛酸(PFOA)和全氟磺酸(PFOS)浓度分别为 0.25 至 6.1μgkg(-1)干重(dw)和 0.58 至 3.7μgkg(-1)dw,大多数采样点的 PFOS 浓度均高于 PFOA。因此,印度尼西亚的沿海水域已经受到防污杀生物剂和全氟烷基化合物的污染。

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