Department of Chemistry and Biochemistry, Jackson State University, 1400 J. R. Lynch Street, P.O. Box 17910, Jackson, MS 39212, USA.
Chem Commun (Camb). 2012 Sep 7;48(69):8631-3. doi: 10.1039/c2cc30767g. Epub 2012 May 10.
An unanticipated anion-water cluster is assembled by one bromide and three highly-ordered "water tetramers" within the cavity of a receptor, providing a perfect C(3) symmetric propeller-shaped bromide-water cluster of Br(H(2)O)(12).
在受体空腔内,一个溴化物和三个高度有序的“水四聚体”组装成一个意想不到的阴离子-水簇,提供了完美的 C(3)对称的螺旋桨状溴-水簇Br(H(2)O)(12)。