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聚合物纳米纤维中嵌入取向排列的金纳米棒:用于等离子体研究和光学传感的新平台。

Polymer nanofibers embedded with aligned gold nanorods: a new platform for plasmonic studies and optical sensing.

机构信息

State Key Laboratory of Modern Optical Instrumentation, Department of Optical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China.

出版信息

Nano Lett. 2012 Jun 13;12(6):3145-50. doi: 10.1021/nl301055f. Epub 2012 May 17.

Abstract

This paper reports the fabrication and characterization of polymer nanofibers embedded with gold nanorods in uniaxial alignment for applications in optical waveguiding and sensing. Using a waveguiding approach, we demonstrated highly efficient excitation of localized surface plasmon resonance in the embedded gold nanorods with a photon-to-plasmon-conversion efficiency as high as 70% for a single nanorod at its longitudinal resonance wavelength. On the basis of waveguiding polymer nanofibers embedded with gold nanorods, we further demonstrated compact optical humidity sensors with a response time of 110 ms and an operation optical power as low as 500 pW.

摘要

本文报道了聚合物纳米纤维的制备和表征,其中嵌入了沿单轴排列的金纳米棒,用于光学波导和传感应用。通过波导方法,我们在嵌入的金纳米棒中展示了局域表面等离子体共振的高效激发,在其纵向共振波长处,单个纳米棒的光子到等离子体转换效率高达 70%。基于嵌入金纳米棒的波导聚合物纳米纤维,我们进一步演示了紧凑的光学湿度传感器,其响应时间为 110ms,操作光功率低至 500pW。

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