1-（二茂铁-1-基甲基）-3-甲基咪唑-3-鎓六氟磷酸酯
1-(Ferrocen-1-ylmeth-yl)-3-methyl-imidazol-3-ium hexa-fluorido-phosphate.
作者信息
Nyamori Vincent O, Zulu Siphesihle M, Omondi Bernard
机构信息
School of Chemistry, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m353. doi: 10.1107/S1600536812008719. Epub 2012 Mar 3.
The crystal structure of the title compound, [Fe(C(5)H(5))(C(10)H(12)N(2))]PF(6), consists of a ferrocene-1-methyl-(3-methyl-imidazolium) cation and a hexa-fluorido-phosphate anion. The ferrocenyl rings are skewed by 6.7 (4)° from the ideal eclipsed conformation. The inter-planar angle between the plane of the substituted cyclo-penta-dienyl ring and that of the imidazole ring is 89.9 (4)°. The crystal packing is stabilized by C-H⋯F hydrogen bonds.
标题化合物[Fe(C₅H₅)(C₁₀H₁₂N₂)]PF₆的晶体结构由一个二茂铁-1-甲基-(3-甲基-咪唑鎓)阳离子和一个六氟磷酸根阴离子组成。二茂铁环与理想的重叠构象呈6.7 (4)°的扭曲。取代的环戊二烯基环平面与咪唑环平面之间的面间角为89.9 (4)°。晶体堆积通过C—H⋯F氢键得以稳定。
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