（η-五甲基环戊二烯基）（η-甲苯）钌（II）六氟磷酸盐
(η-Penta-methyl-cyclo-penta-dien-yl)(η-toluene)-ruthenium(II) hexa-fluorido-phosphate.
作者信息
O Wylie W N, Lough Alan J, Morris Robert H
机构信息
Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 3H6.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 15;66(Pt 10):m1264. doi: 10.1107/S1600536810036299.
In the title complex, [Ru(C(7)H(8))(C(10)H(15))]PF(6), the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclo-penta-dienyl ring is 1.811 (5) Å. The crystal structure is stabilized by weak C-H⋯F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies.
在标题配合物[Ru(C₇H₈)(C₁₀H₁₅)]PF₆中，阳离子位于一个镜面平面上，阴离子位于一个对称中心上。钌原子与苯环质心之间的距离为1.706(5) Å，钌原子与环戊二烯基环之间的距离为1.811(5) Å。晶体结构通过弱的C-H⋯F氢键得以稳定。位于镜面平面上的甲基的H原子在两个位置上无序分布，占有率相等。
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