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（η-五甲基环戊二烯基）（η-甲苯）钌（II）六氟磷酸盐

(η-Penta-methyl-cyclo-penta-dien-yl)(η-toluene)-ruthenium(II) hexa-fluorido-phosphate.

作者信息

O Wylie W N, Lough Alan J, Morris Robert H

机构信息

Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 3H6.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 15;66(Pt 10):m1264. doi: 10.1107/S1600536810036299.

DOI:10.1107/S1600536810036299
PMID:21587411
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983397/
Abstract

In the title complex, [Ru(C(7)H(8))(C(10)H(15))]PF(6), the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclo-penta-dienyl ring is 1.811 (5) Å. The crystal structure is stabilized by weak C-H⋯F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies.

摘要

在标题配合物[Ru(C₇H₈)(C₁₀H₁₅)]PF₆中，阳离子位于一个镜面平面上，阴离子位于一个对称中心上。钌原子与苯环质心之间的距离为1.706(5) Å，钌原子与环戊二烯基环之间的距离为1.811(5) Å。晶体结构通过弱的C-H⋯F氢键得以稳定。位于镜面平面上的甲基的H原子在两个位置上无序分布，占有率相等。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d79/2983397/e82d2b6284da/e-66-m1264-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d79/2983397/f956359fdf15/e-66-m1264-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d79/2983397/e82d2b6284da/e-66-m1264-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d79/2983397/f956359fdf15/e-66-m1264-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d79/2983397/e82d2b6284da/e-66-m1264-fig2.jpg

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本文引用的文献

1
The hydrogenation of molecules with polar bonds catalyzed by a ruthenium(II) complex bearing a chelating N-heterocyclic carbene with a primary amine donor.含手性氮杂环卡宾配体的钌(II)配合物催化的极性键分子氢化反应。
Chem Commun (Camb). 2010 Nov 21;46(43):8240-2. doi: 10.1039/c0cc02664f. Epub 2010 Sep 27.
2
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
3
Selective cytotoxic Ru(II) arene Cp* complex salts [R-PhRuCp*](+)X(-) for X = BF4(-), PF6(-), and BPh4(-).
选择性细胞毒性钌（II）芳烃茂金属阳离子配合物盐[R-PhRuCp*](+)X(-)，其中X = BF4(-)、PF6(-)和BPh4(-) 。
Inorg Chem. 2008 Oct 6;47(19):8589-91. doi: 10.1021/ic801159f. Epub 2008 Sep 11.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
5
An empirical correction for absorption anisotropy.吸收各向异性的经验校正
Acta Crystallogr A. 1995 Jan 1;51 ( Pt 1):33-8. doi: 10.1107/s0108767394005726.