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六氟磷酸氯代[1-(二苯基膦基)钴茂鎓]金(I)

Chlorido[1-(diphenyl-phosphan-yl)cobaltocenium]gold(I) hexa-fluoridophosphate.

作者信息

Wu Xiang-Hua

机构信息

College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650092, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m798. doi: 10.1107/S1600536811018769. Epub 2011 May 25.

DOI:10.1107/S1600536811018769
PMID:21754675
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120450/
Abstract

In the cobaltocenium group of the title compound, [AuCo(C(5)H(5))(C(17)H(14)P)Cl]PF(6), the substituted cyclo-penta-dienyl (Cps) and the unsubstituted cyclo-penta-dienyl (Cp) ring planes are almost parallel, making a dihedral angle of 3.1 (3)°. The C atoms in Cp and Cps are in an eclipsed conformation. The Au(I) atom is coordinated by a P atom from the diphenyl-phosphanyl group and a Cl atom in an almost linear arrangement [P-Au-Cl = 178.15-(7)°]. Two hexa-fluorido-phosphate anions are each located on a twofold rotation axis. In the crystal, the complex cations and hexa-fluorido-phosphate anions are linked via inter-molecular C-H⋯F hydrogen bonds.

摘要

在标题化合物[AuCo(C₅H₅)(C₁₇H₁₄P)Cl]PF₆的钴茂基团中，取代的环戊二烯基（Cps）和未取代的环戊二烯基（Cp）环平面几乎平行，二面角为3.1（3）°。Cp和Cps中的C原子呈重叠构象。Au（I）原子由二苯基膦基的一个P原子和一个Cl原子以几乎线性的排列方式配位[P-Au-Cl = 178.15-（7）°]。两个六氟磷酸根阴离子各自位于一个二重旋转轴上。在晶体中，配合物阳离子和六氟磷酸根阴离子通过分子间C-H⋯F氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dad1/3120450/a25ae2dc226a/e-67-0m798-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dad1/3120450/1432ff4a576c/e-67-0m798-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dad1/3120450/a25ae2dc226a/e-67-0m798-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dad1/3120450/1432ff4a576c/e-67-0m798-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dad1/3120450/a25ae2dc226a/e-67-0m798-fig2.jpg

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本文引用的文献

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