• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

二水合双（1H-苯并咪唑-κN(3)）双-[2-(萘-1-基)乙酸根-κ(2)O,O']镍(II)

Bis(1H-benzimidazole-κN(3))bis-[2-(naphthalen-1-yl)acetato-κ(2)O,O']nickel(II) monohydrate.

作者信息

Yin Fu-Jun, Han Li-Jun, Hong Zhao, Xu Xing-You, Ren Li

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m416. doi: 10.1107/S1600536812010021. Epub 2012 Mar 14.

DOI:10.1107/S1600536812010021
PMID:22589796
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3343822/
Abstract

In the title compound, [Ni(C(12)H(9)O(2))(2)(C(7)H(6)N(2))(2)]·H(2)O, The Ni(II) cation is located on a twofold rotation axis and is six-coordinated in a distorted NiN(2)O(4) octa-hedral geometry. The asymmetric unit consists of a nickel(II) ion, one 2-(naphthalen-1-yl)acetate anion, a neutral benzotriazole ligand and one half of a lattice water mol-ecule. The crystal packing is stabilized by O-H⋯O and N-H⋯O hydrogen bonds. The title compound is isotypic with its Cd(II) analogue.

摘要

在标题化合物[Ni(C₁₂H₉O₂)₂(C₇H₆N₂)₂]·H₂O中，Ni(II)阳离子位于二重旋转轴上，以扭曲的NiN₂O₄八面体几何构型进行六配位。不对称单元由一个镍(II)离子、一个2-(萘-1-基)乙酸根阴离子、一个中性苯并三唑配体和半个晶格水分子组成。晶体堆积通过O—H⋯O和N—H⋯O氢键得以稳定。标题化合物与其Cd(II)类似物为同型体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d9a/3343822/5ba6b8efc97b/e-68-0m416-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d9a/3343822/f02f200d7bcd/e-68-0m416-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d9a/3343822/5ba6b8efc97b/e-68-0m416-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d9a/3343822/f02f200d7bcd/e-68-0m416-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d9a/3343822/5ba6b8efc97b/e-68-0m416-fig2.jpg

相似文献

1
Bis(1H-benzimidazole-κN(3))bis-[2-(naphthalen-1-yl)acetato-κ(2)O,O']nickel(II) monohydrate.二水合双（1H-苯并咪唑-κN(3)）双-[2-(萘-1-基)乙酸根-κ(2)O,O']镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m416. doi: 10.1107/S1600536812010021. Epub 2012 Mar 14.
2
Bis(1H-benzimidazole-κN)bis-[2-(naphthalen-1-yl)acetato-κO,O']manganese(II) monohydrate.二水合双（1H-苯并咪唑-κN）双-[2-（萘-1-基）乙酸根-κO，O']锰（II）
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m328. doi: 10.1107/S1600536812007441. Epub 2012 Feb 24.
3
Tetra-aqua-bis-(N,N-dimethyl-formamide-κO)zinc(II) bis-[(2-{3-[2-(carboxyl-ato-meth-oxy-κ(2)O,O')phen-yl]pyrazol-1-yl-κN(2)}acetato-κO)chloridozincate(II)].四水合双（N，N - 二甲基甲酰胺 - κO）锌（II）双[（2 - {3 - [2 - （羧基甲氧基 - κ（2）O，O'）苯基]吡唑 - 1 - 基 - κN（2）}乙酸根 - κO）氯锌酸（II）]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m817. doi: 10.1107/S1600536812023045. Epub 2012 May 26.
4
Bis[μ-2-(2,4-difluoro-phen-yl)-1,3-bis-(1,2,4-triazol-1-yl)propan-2-olato-κN,O:O,N]bis-[(acetato-κO,O')nickel(II)] methanol hemisolvate.双[μ-2-(2,4-二氟苯基)-1,3-双-(1,2,4-三唑-1-基)丙-2-醇根合-κN,O:O,N]双[(乙酸根合-κO,O')镍(II)]甲醇半溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 19;66(Pt 1):m75-6. doi: 10.1107/S160053680905377X.
5
Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis-(ethanol-κO)nickel(II).双[2-(1H-苯并咪唑-2-基)乙酸根-κ(2)N(3),O]双(乙醇-κO)镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1461. doi: 10.1107/S160053681204514X. Epub 2012 Nov 7.
6
Diaqua-bis-(1-methyl-1H-imidazole-κN(3))bis-[2-(naphthalen-1-yl)acetato-κO]cobalt(II).二水合双（1-甲基-1H-咪唑-κN(3)）双[2-（萘-1-基）乙酸根-κO]钴（II）
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m533. doi: 10.1107/S1600536812013505. Epub 2012 Apr 4.
7
(Acetato-κO)(aqua-κO)(2-{bis-[(3,5-dimethyl-1H-pyrazol-1-yl-κN(2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate.一水合高氯酸（乙酸根 - κO）（水 - κO）（2 - {双 - [(3,5 - 二甲基 - 1H - 吡唑 - 1 - 基 - κN(2))甲基]氨基 - κN}乙醇 - κO）镍（II）
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m399. doi: 10.1107/S1600536812007970. Epub 2012 Mar 10.
8
Bis(μ-cyclo-hexane-1,4-dicarboxyl-ato)bis-{aqua-[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate.一水合双（μ-环己烷-1,4-二羧酸根）双-{水合-[1-(1H-咪唑并[4,5-f][1,10]菲咯啉-2-基)萘-2-醇]镉}
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 12;67(Pt 3):m325. doi: 10.1107/S1600536811004727.
9
Di-μ-acetato-κO:O-bis-{(acetato-κO,O')bis-[3-(1H-imidazol-1-yl-κN)-1-phenyl-propan-1-one]cadmium} tetra-hydrate.二-μ-乙酸根-κO:O-双-{（乙酸根-κO,O'）双-[3-(1H-咪唑-1-基-κN)-1-苯基-丙-1-酮]镉}四水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1884. doi: 10.1107/S1600536811050021. Epub 2011 Nov 30.
10
catena-Poly[[(acetato-κO,O')(methanol-κO)cadmium(II)]-μ-[1,2-bis-(1H-benzimid-azol-2-yl)ethane]-κN:N-[(acetato-κO,O')(methanol-κO)cadmium(II)]-di-μ-chlorido].链状聚[[(乙酸根 - κO,O')(甲醇 - κO)镉(II)] - μ - [1,2 - 双-(1H - 苯并咪唑 - 2 - 基)乙烷] - κN:N - [(乙酸根 - κO,O')(甲醇 - κO)镉(II)] - 二 - μ - 氯化物]
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 28;66(Pt 5):m578. doi: 10.1107/S1600536810014753.

引用本文的文献

1
Metal Complexes with Naphthalene-Based Acetic Acids as Ligands: Structure and Biological Activity.基于萘基乙酸的金属配合物：结构与生物活性。
Molecules. 2023 Feb 26;28(5):2171. doi: 10.3390/molecules28052171.

本文引用的文献

1
Bis(1-methyl-1H-imidazole-κN)bis-[2-(naphthalen-1-yl)acetato-κO]copper(II) monohydrate.一水合双（1-甲基-1H-咪唑-κN）双-[2-（萘-1-基）乙酸根-κO]铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1821. doi: 10.1107/S1600536811049439. Epub 2011 Nov 25.
2
Bis-(2-methyl-1H-imidazole-κN)bis[2-(naphthalen-2-yl)acetato-κO]copper(II).双（2-甲基-1H-咪唑-κN）双[2-（萘-2-基）乙酸根-κO]铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1772. doi: 10.1107/S1600536811047969. Epub 2011 Nov 16.
3
(5,5'-Dimethyl-2,2'-bipyridine-κN,N')(1-naphthyl-acetato-κO)(1-naphthyl-acetato-κO,O')zinc hemihydrate.
半水合（5,5'-二甲基-2,2'-联吡啶-κN,N'）（1-萘基乙酸根-κO）（1-萘基乙酸根-κO,O'）锌
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m606. doi: 10.1107/S1600536811013353. Epub 2011 Apr 16.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.