Research Center for Applied Sciences, Academic Sinica, Taipei, 115, Taiwan.
Nanoscale Res Lett. 2012 May 16;7(1):257. doi: 10.1186/1556-276X-7-257.
: We have theoretically studied the thermoelectric properties of serially coupled quantum dots (SCQDs) embedded in an insulator connected to metallic electrodes. In the framework of Keldysh Green's function technique, the Landauer formula of transmission factor is obtained using the equation of motion method. Based on such analytical expressions of charge and heat currents, we calculate the electrical conductance, Seebeck coefficient, electron thermal conductance, and figure of merit (ZT) of SCQDs in the linear response regime. The effects of interdot hopping and electron Coulomb interactions on ZT are analyzed. We demonstrate that ZT is not a monotonic increasing function of interdot electron hopping strength (tc). We also show that in the absence of phonon thermal conductance, SCQD can reach the Carnot efficiency as tcapproaches zero.
: 我们从理论上研究了嵌入在与金属电极相连的绝缘体中的串联量子点 (SCQDs) 的热电性质。在 Keldysh Green 函数技术的框架内,使用运动方程方法获得了传输因子的 Landauer 公式。基于电荷和热流的这种解析表达式,我们在线性响应区域计算了 SCQDs 的电导率、Seebeck 系数、电子热导率和品质因数 (ZT)。分析了点间跃迁和电子库仑相互作用对 ZT 的影响。我们证明了 ZT 不是点间电子跃迁强度 (tc) 的单调递增函数。我们还表明,在不存在声子热导率的情况下,当 tc 趋近于零时,SCQD 可以达到卡诺效率。