Department of Materials Science and Engineering, Inha University, 253 Youghyun, Incheon 402-751, South Korea.
Adv Mater. 2012 Jul 3;24(25):3373-7. doi: 10.1002/adma.201200505. Epub 2012 May 31.
An extremely thin bilayer electrolyte consisting of yttria-stabilized zirconia (YSZ) and gadolinia-doped ceria (GDC) is successfully fabricated on a sintered NiO-YSZ substrate. Major processing flaws are effectively eliminated by applying local constraints to YSZ nanoparticles, and excellent open circuit voltage and cell performance are demonstrated in a solid oxide fuel cell (SOFC) at intermediate operating temperatures.
成功在烧结的 NiO-YSZ 基底上制备了由钇稳定氧化锆(YSZ)和掺钆氧化铈(GDC)组成的极薄双层电解质。通过对 YSZ 纳米颗粒施加局部约束,有效消除了主要的加工缺陷,并在中温固体氧化物燃料电池(SOFC)中展示了优异的开路电压和电池性能。