• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

具有旋涂氧化钇稳定氧化锆/钆掺杂二氧化铈双层电解质的固体氧化物燃料电池。

Solid oxide fuel cell with a spin-coated yttria stabilized zirconia/gadolinia doped ceria bi-layer electrolyte.

作者信息

Li Jingyu, Fan Lijun, Hou Nianjun, Zhao Yicheng, Li Yongdan

机构信息

State Key Laboratory of Chemical Engineering (Tianjin University), Tianjin Key Laboratory of Applied Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University Tianjin 300072 China

Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) Tianjin 300072 China.

出版信息

RSC Adv. 2022 May 3;12(21):13220-13227. doi: 10.1039/d2ra02035a. eCollection 2022 Apr 28.

DOI:10.1039/d2ra02035a
PMID:35520125
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9063383/
Abstract

A thin yttria stabilized zirconia (YSZ)/gadolinia doped ceria (GDC) bi-layer membrane is fabricated through the slurry spin coating technique and used as an electrolyte of a solid oxide fuel cell with LaSrCoFeO as the cathode. The viscosity of the YSZ slurry is controlled by adding ethanol in the terpineol solvent, which shows a negligible effect on the thickness but a remarkable influence on the porosity of the YSZ film. The thickness of the YSZ layer increases with the YSZ content in the slurry. The YSZ films are pre-sintered at various temperatures, and the one sintered at 1200 °C has a moderate interaction with the GDC slurry, forming a 10 μm-thick YSZ/GDC bilayer with a low porosity and a low ohmic resistance. The corresponding single cell shows a maximum power density of 1480 mW cm at 750 °C.

摘要

通过浆料旋涂技术制备了一种薄的氧化钇稳定氧化锆（YSZ）/钆掺杂二氧化铈（GDC）双层膜，并将其用作以LaSrCoFeO为阴极的固体氧化物燃料电池的电解质。通过在萜品醇溶剂中添加乙醇来控制YSZ浆料的粘度，这对厚度的影响可忽略不计，但对YSZ膜的孔隙率有显著影响。YSZ层的厚度随浆料中YSZ含量的增加而增加。YSZ膜在不同温度下进行预烧结，在1200℃烧结的膜与GDC浆料有适度的相互作用，形成了具有低孔隙率和低欧姆电阻的10μm厚的YSZ/GDC双层膜。相应的单电池在750℃时显示出1480 mW/cm²的最大功率密度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/e0e1ae21f891/d2ra02035a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/8580c8828e31/d2ra02035a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/a1f235536b65/d2ra02035a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/2ea9765c5b80/d2ra02035a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/94666c7f2b0c/d2ra02035a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/06294bdb7c79/d2ra02035a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/87a2faf79315/d2ra02035a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/3b889fda36d7/d2ra02035a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/e0e1ae21f891/d2ra02035a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/8580c8828e31/d2ra02035a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/a1f235536b65/d2ra02035a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/2ea9765c5b80/d2ra02035a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/94666c7f2b0c/d2ra02035a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/06294bdb7c79/d2ra02035a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/87a2faf79315/d2ra02035a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/3b889fda36d7/d2ra02035a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf93/9063383/e0e1ae21f891/d2ra02035a-f8.jpg

相似文献

1
Solid oxide fuel cell with a spin-coated yttria stabilized zirconia/gadolinia doped ceria bi-layer electrolyte.具有旋涂氧化钇稳定氧化锆/钆掺杂二氧化铈双层电解质的固体氧化物燃料电池。
RSC Adv. 2022 May 3;12(21):13220-13227. doi: 10.1039/d2ra02035a. eCollection 2022 Apr 28.
2
High-Performance (Ce, Zr)O-Free Solid Oxide Fuel Cell with an Active-Sintered Cathode Interface and a Low-Temperature Densified Micron-Scale Barrier Layer.具有活性烧结阴极界面和低温致密微米级阻挡层的高性能无（铈、锆）氧化物固体氧化物燃料电池。
ACS Appl Mater Interfaces. 2023 Aug 30;15(34):40588-40594. doi: 10.1021/acsami.3c08019. Epub 2023 Aug 17.
3
Polarization-Induced Interface and Sr Segregation of in Situ Assembled LaSrCoFeO Electrodes on YO-ZrO Electrolyte of Solid Oxide Fuel Cells.原位组装的 LaSrCoFeO 电极在固体氧化物燃料电池的 YO-ZrO 电解质中的极化诱导界面和 Sr 偏析。
ACS Appl Mater Interfaces. 2016 Nov 23;8(46):31729-31737. doi: 10.1021/acsami.6b11665. Epub 2016 Nov 11.
4
Oxygen surface exchange properties and surface segregation behavior of nanostructured LaSrCoFeO thin film cathodes.纳米结构 LaSrCoFeO 薄膜阴极的氧表面交换性能和表面偏析行为。
Phys Chem Chem Phys. 2019 Mar 27;21(13):7183-7195. doi: 10.1039/c9cp00606k.
5
Solid Oxide Fuel Cells with Magnetron Sputtered Single-Layer SDC and Multilayer SDC/YSZ/SDC Electrolytes.采用磁控溅射单层SDC和多层SDC/YSZ/SDC电解质的固体氧化物燃料电池。
Membranes (Basel). 2023 Jun 5;13(6):585. doi: 10.3390/membranes13060585.
6
The Properties of Intermediate-Temperature Solid Oxide Fuel Cells with Thin Film Gadolinium-Doped Ceria Electrolyte.具有薄膜钆掺杂二氧化铈电解质的中温固体氧化物燃料电池的特性
Membranes (Basel). 2022 Sep 17;12(9):896. doi: 10.3390/membranes12090896.
7
Fabrication of low-temperature solid oxide fuel cells with a nanothin protective layer by atomic layer deposition.采用原子层沉积法制备具有纳米级超薄保护层的低温固体氧化物燃料电池。
Nanoscale Res Lett. 2013 Jan 23;8(1):48. doi: 10.1186/1556-276X-8-48.
8
PEALD YSZ-based bilayer electrolyte for thin film-solid oxide fuel cells.基于 PEALD YSZ 的双层电解质用于薄膜固态氧化物燃料电池。
Nanotechnology. 2016 Oct 14;27(41):415402. doi: 10.1088/0957-4484/27/41/415402. Epub 2016 Sep 5.
9
Extremely thin bilayer electrolyte for solid oxide fuel cells (SOFCs) fabricated by chemical solution deposition (CSD).通过化学溶液沉积（CSD）制备的用于固体氧化物燃料电池（SOFC）的极薄双层电解质。
Adv Mater. 2012 Jul 3;24(25):3373-7. doi: 10.1002/adma.201200505. Epub 2012 May 31.
10
Hierarchically oriented macroporous anode-supported solid oxide fuel cell with thin ceria electrolyte film.具有薄二氧化铈电解质膜的分级定向大孔阳极支撑固体氧化物燃料电池。
ACS Appl Mater Interfaces. 2014 Apr 9;6(7):5130-6. doi: 10.1021/am5003662. Epub 2014 Mar 21.

引用本文的文献

1
Overview of Recent Advances in Rare-Earth High-Entropy Oxides as Multifunctional Materials for Next-Gen Technology Applications.稀土高熵氧化物作为下一代技术应用的多功能材料的最新进展综述
Molecules. 2025 Feb 27;30(5):1082. doi: 10.3390/molecules30051082.
2
Boosting Electrochemical Performance via Extra-Role of La-Doped CeO Interlayer for "Oxygen Provider" at High-Current SOFC Operation.通过La掺杂CeO中间层在高电流固体氧化物燃料电池运行中作为“氧气供应者”的额外作用提高电化学性能。
Adv Sci (Weinh). 2024 Dec;11(46):e2402348. doi: 10.1002/advs.202402348. Epub 2024 Sep 27.
3
Superior Electrochemical Performance of a CeGdO/ZrScO Thin Bilayer-Protected Gadolinium-Doped Ceria Electrolyte in Intermediate-Temperature Solid Oxide Fuel Cells.

本文引用的文献

1
Strategies for Carbon and Sulfur Tolerant Solid Oxide Fuel Cell Materials, Incorporating Lessons from Heterogeneous Catalysis.兼顾多相催化经验的耐碳硫固体氧化物燃料电池材料策略
Chem Rev. 2016 Nov 23;116(22):13633-13684. doi: 10.1021/acs.chemrev.6b00284. Epub 2016 Nov 9.
2
Strongly correlated perovskite fuel cells.强关联钙钛矿燃料电池。
Nature. 2016 Jun 9;534(7606):231-4. doi: 10.1038/nature17653. Epub 2016 May 16.
3
Readily processed protonic ceramic fuel cells with high performance at low temperatures.易于低温处理的质子陶瓷燃料电池，具有高性能。
CeGdO/ZrScO 双层薄膜保护的钆掺杂二氧化铈电解质在中温固体氧化物燃料电池中的卓越电化学性能
ACS Omega. 2023 Feb 16;8(8):8011-8018. doi: 10.1021/acsomega.2c07855. eCollection 2023 Feb 28.
Science. 2015 Sep 18;349(6254):1321-6. doi: 10.1126/science.aab3987. Epub 2015 Jul 23.
4
Defect chemistry of singly and doubly doped ceria: correlation between ion transport and energetics.单掺杂和双掺杂氧化铈的缺陷化学：离子输运与能量学的关系。
Angew Chem Int Ed Engl. 2014 Sep 1;53(36):9517-21. doi: 10.1002/anie.201404618. Epub 2014 Jul 9.
5
A family of oxide ion conductors based on the ferroelectric perovskite Na0.5Bi0.5TiO3.基于铁电钙钛矿 Na0.5Bi0.5TiO3 的氧化物离子导体家族。
Nat Mater. 2014 Jan;13(1):31-5. doi: 10.1038/nmat3782. Epub 2013 Nov 10.
6
Monoclinic Sr(1-x)Na(x)SiO(3-0.5x): new superior oxide ion electrolytes.钙钛矿型 Sr(1-x)Na(x)SiO(3-0.5x)：新型优越的氧离子导体。
J Am Chem Soc. 2013 Jul 10;135(27):10149-54. doi: 10.1021/ja4042737. Epub 2013 Jul 1.
7
Lowering the temperature of solid oxide fuel cells.降低固体氧化物燃料电池的温度。
Science. 2011 Nov 18;334(6058):935-9. doi: 10.1126/science.1204090.
8
Materials for fuel-cell technologies.用于燃料电池技术的材料。
Nature. 2001 Nov 15;414(6861):345-52. doi: 10.1038/35104620.