ISMN-CNR, INAF, c/o Department of Chemistry, University of Rome La Sapienza, p.le A. Moro 5, Rome, 00185, Italy.
Orig Life Evol Biosph. 2012 Jun;42(2-3):179-86. doi: 10.1007/s11084-012-9285-2. Epub 2012 Jun 2.
Naphthalene is an interesting candidate to study in the framework of organic delivery to planetary surfaces as well as in the origin of life. Additionally, naphthalene is of environmental interest, because of its chronic and acute effects on living systems, such as humans and animals (e.g. moths). Naphthalene has been well studied in both fields. In this paper we give an overview of radiolytic studies of naphthalene in the presence of both liquid water and water ice. From our review it appears that OH radicals are formed both in liquid water and in interstellar ices and that these radicals play a considerable role in the degradation of naphthalene. However, it also appears that upon irradiation of naphthalene in liquid water, hydrogen peroxide, a species that accelerates naphthalene degradation, is formed. Based on this review we suggest that the role of hydrogen peroxide in interstellar ices should be further investigated.
萘是研究有机物质向行星表面输送以及生命起源的一个有趣的候选物。此外,由于萘对人类和动物等生命系统具有慢性和急性影响,因此它也具有环境意义(例如蛾类)。在这两个领域中,萘都已经得到了充分的研究。在本文中,我们综述了在液态水和水冰存在下萘的辐射分解研究。从我们的综述中可以看出,OH 自由基在液态水中和星际冰中都会形成,并且这些自由基在萘的降解中起着相当大的作用。然而,似乎在液态水中辐照萘时,会形成一种加速萘降解的物质——过氧化氢。基于这篇综述,我们建议进一步研究过氧化氢在星际冰中的作用。