从苯乙烯和芳烃中直接合成菲。
Straightforward synthesis of phenanthrenes from styrenes and arenes.
机构信息
Beijing National Laboratory of Molecular Sciences, College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871, China.
出版信息
Chem Commun (Camb). 2012 Jul 18;48(56):7028-30. doi: 10.1039/c2cc33100d. Epub 2012 Jun 11.
PMID:22683834
Abstract
Semi-one-pot synthesis of phenanthrenes from styrenes and arenes was developed through cross-dehydrogenative coupling. A sequence of Heck-type coupling and photo-cyclization were involved and a variety of functionalities were tolerated. This method provides an effective and practical protocol towards the synthesis of substituted phenanthrenes.
摘要
通过交叉脱氢偶联，开发了从苯乙烯和芳烃合成菲的半一锅法。该过程涉及 Heck 型偶联和光环化反应，多种官能团都能兼容。该方法为取代菲的合成提供了一种有效且实用的方案。
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