钯催化苯炔与N-取代-N-(2-卤苯基)甲酰胺的环化反应：菲啶酮的合成
Palladium-catalyzed annulation of benzynes with N-substituted-N-(2-halophenyl)formamides: synthesis of phenanthridinones.
作者信息
Yang Yuan, Huang Hui, Wu Lijun, liang Yun
机构信息
National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, China.
出版信息
Org Biomol Chem. 2014 Aug 7;12(29):5351-5. doi: 10.1039/c4ob00997e.
A novel and efficient procedure for the synthesis of N-substituted phenanthridinones via palladium-catalyzed annulation of benzynes with N-substituted-N-(2-halophenyl)formamides has been developed. This methodology constructs two new C-C bonds via an arylation/annulation process, and provides the desired products in good yields.
通过钯催化苯炔与N-取代-N-(2-卤苯基)甲酰胺的环化反应合成N-取代菲啶酮的一种新颖且高效的方法已被开发出来。该方法通过芳基化/环化过程构建了两个新的C-C键，并以良好的产率提供所需产物。
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