酶促化学合成法从香叶基二磷酸合成警报信息素 (+)-马鞭草烯酮。
Chemoenzymatic synthesis of the alarm pheromone (+)-verbenone from geranyl diphosphate.
机构信息
School of Chemistry and Cardiff Catalysis Institute, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, United Kingdom.
出版信息
Chem Commun (Camb). 2012 Jul 18;48(56):7040-2. doi: 10.1039/c2cc32883f. Epub 2012 Jun 11.
PMID:22684271
Abstract
The enzyme-guided asymmetric synthesis of (+)-verbenone from geranyl diphosphate in a simple two-step, one pot transformation highlights the potential of chemoenzymatic procedures for the generation of high-value terpenoids.
摘要
酶促不对称合成（+）-马鞭草酮从香叶基二磷酸在一个简单的两步，一锅转化突出了化学酶程序的潜力为高价值的萜烯的产生。
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