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作为赝电容材料的甜甜圈状 Ni(OH)₂-Co(OH)₂ 复合材料的制备及其电化学性能。

Preparation and electrochemical performances of doughnut-like Ni(OH)₂-Co(OH)₂ composites as pseudocapacitor materials.

机构信息

Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Institute of New Energy Material Chemistry, Nankai University, Tianjin 300071, China.

出版信息

Nanoscale. 2012 Aug 7;4(15):4498-503. doi: 10.1039/c2nr30936j. Epub 2012 Jun 8.

Abstract

Doughnut-like nanostructured Ni(OH)(2)-Co(OH)(2) composites were prepared by combining hydrothermal and chemical deposition routes. The electrochemical performances of the composites were investigated as pseudocapacitor materials through galvanostatic charge-discharge and cyclic voltammetry tests. The Ni(OH)(2)-Co(OH)(2) composites delivered a specific capacitance of 2193 F g(-1) at 2 A g(-1) and 1398 F g(-1) at 20 A g(-1), much higher than those of pristine Ni(OH)(2). The enhancement of the overall electrochemical performances is ascribed to the synergetic contribution from nanostructured Ni(OH)(2) and electrically conductive CoOOH forming in the charge process.

摘要

通过水热法和化学沉积相结合的方法制备了类甜甜圈结构的 Ni(OH)(2)-Co(OH)(2) 复合材料。通过恒电流充放电和循环伏安测试,将复合材料作为赝电容器材料进行了电化学性能研究。在 2 A g(-1) 的电流密度下,Ni(OH)(2)-Co(OH)(2) 复合材料的比电容为 2193 F g(-1),在 20 A g(-1) 的电流密度下,比电容为 1398 F g(-1),远高于纯 Ni(OH)(2)。整体电化学性能的提高归因于在充电过程中形成的纳米结构 Ni(OH)(2)和导电 CoOOH 的协同贡献。

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