钯（II）催化的非芳族烯酰胺的直接烯基化反应。
Palladium(II)-catalyzed direct alkenylation of nonaromatic enamides.
机构信息
Institut de Chimie Organique et Analytique, UMR 7311 CNRS, rue de Chartres, Université d'Orléans, F-45067 Orléans Cedex 2, France.
出版信息
Org Lett. 2012 Jul 6;14(13):3304-7. doi: 10.1021/ol301249n. Epub 2012 Jun 13.
PMID:22694149
Abstract
A mild and efficient method for the direct alkenylation of nonaromatic enamides was achieved through a palladium(II)-catalyzed C-H functionalization. The reaction scope includes cyclic and acyclic enamides and a range of activated alkenes. This approach represents the first successful direct C(3)-functionalization of nonaromatic cyclic enamides.
摘要
通过钯（II）催化的 C-H 功能化反应，实现了一种温和、高效的非芳族烯酰胺直接烯基化方法。该反应的范围包括环状和非环状烯酰胺以及一系列活化的烯烃。该方法代表了首例成功的非芳族环状烯酰胺的直接 C(3)-功能化。
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