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提高透明玻璃上仿蛾眼纳米柱的减反特性:平面减反和颜色调谐。

Improved antireflection properties of moth eye mimicking nanopillars on transparent glass: flat antireflection and color tuning.

机构信息

Department of Nature-Inspired Nanoconvergence Systems, Korea Institute of Machinery and Materials, 156 Gajeongbuk-Ro, Deajeon 305-343, Republic of Korea.

出版信息

Nanoscale. 2012 Aug 7;4(15):4603-10. doi: 10.1039/c2nr30787a. Epub 2012 Jun 18.

Abstract

The sub-wavelength structures in moth eyes exhibit fascinating antireflective properties over the broadband wavelength region and at large incident angle by generating an air-mixed heterogeneous optical interface. In this work, antireflective behavior of transparent glass is observed with the elaborate controls of the nanopillar morphology. The reflectance spectrum shows a red shift and a notable light scattering with increase of the height of the nanopillars. The nanopillar arrays with a pointed cone shape have better optical performance in visible range than the rounded cone shape which is typical antireflective nanostructures in nature. Based on the observed antireflective behaviors, the flat and low value reflectance spectrum in the visible wavelength range is demonstrated by moth eye mimicking nanostructures on both sides of a glass surface. It is a unique strategy to realize a flat and broadband spectrum in the visible range showing 99% transparency via the appropriate matching of nanopillar height on the front and back sides of glass. The controlled reflection based color tuning on the antireflective and transparent glass is also obtained by adjusting the height of the nanopillar arrays on both sides. The visibility and self-cleaning ability of moth eye mimicking glass are examined for practical applications such as antireflection and self-cleaning.

摘要

在宽带波长区域和大入射角下,飞蛾眼睛中的亚波长结构通过产生空气混合的非均匀光学界面,表现出迷人的抗反射特性。在这项工作中,通过精细控制纳米柱形态,观察到透明玻璃的抗反射行为。随着纳米柱高度的增加,反射光谱显示出红移和明显的光散射。与自然界中典型的抗反射纳米结构(即圆形锥形)相比,具有尖锥形的纳米柱阵列在可见光范围内具有更好的光学性能。基于观察到的抗反射行为,通过在玻璃表面两侧模拟飞蛾眼纳米结构,在可见光波长范围内实现了平坦且低反射率的光谱,其反射率为 99%。通过适当匹配玻璃前后表面纳米柱的高度,实现了在可见光谱范围内具有平坦和宽带光谱的独特策略,同时具有 99%的透光率。通过调整两侧纳米柱阵列的高度,还可以获得抗反射和透明玻璃的可控反射颜色调谐。为了实现抗反射和自清洁等实际应用,还对模拟飞蛾眼的玻璃的可视性和自清洁能力进行了检查。

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