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2-（4-甲氧基苯氧基）乙酰肼

2-(4-Meth-oxy-phen-oxy)acetohydrazide.

作者信息

Liu Gang, Gao Jie

机构信息

College of Food Engineering, Jilin Teachers' Institute of Engineering and Technology, 130052 Changchun, Jilin, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1969. doi: 10.1107/S160053681202435X. Epub 2012 May 31.

DOI:10.1107/S160053681202435X
PMID:22719715
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3379517/
Abstract

The title compound, C(9)H(12)N(2)O(3), was synthesized by the reaction of ethyl 2-(4-meth-oxy-phen-oxy)acetate with hydrazine hydrate in ethanol. In the acetohydrazide group, the N-N bond is relatively short [1.413 (2) Å], suggesting some degree of electronic delocalization in the mol-ecule. In the crystal, mol-ecules are linked into sheets lying parallel to the ab plane by N-H⋯N and N-H⋯O hydrogen bonds.

摘要

标题化合物C(9)H(12)N(2)O(3)是由2-(4-甲氧基苯氧基)乙酸乙酯与水合肼在乙醇中反应合成的。在乙酰肼基团中，N-N键相对较短[1.413 (2) Å]，表明分子中存在一定程度的电子离域。在晶体中，分子通过N-H⋯N和N-H⋯O氢键连接成平行于ab平面的片层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37a4/3379517/f04719ba00a7/e-68-o1969-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37a4/3379517/e0b488673822/e-68-o1969-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37a4/3379517/f04719ba00a7/e-68-o1969-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37a4/3379517/e0b488673822/e-68-o1969-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37a4/3379517/f04719ba00a7/e-68-o1969-fig2.jpg

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