Liu Gang, Gao Jie
College of Food Engineering, Jilin Teachers' Institute of Engineering and Technology, 130052 Changchun, Jilin, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1969. doi: 10.1107/S160053681202435X. Epub 2012 May 31.
The title compound, C(9)H(12)N(2)O(3), was synthesized by the reaction of ethyl 2-(4-meth-oxy-phen-oxy)acetate with hydrazine hydrate in ethanol. In the acetohydrazide group, the N-N bond is relatively short [1.413 (2) Å], suggesting some degree of electronic delocalization in the mol-ecule. In the crystal, mol-ecules are linked into sheets lying parallel to the ab plane by N-H⋯N and N-H⋯O hydrogen bonds.
标题化合物C(9)H(12)N(2)O(3)是由2-(4-甲氧基苯氧基)乙酸乙酯与水合肼在乙醇中反应合成的。在乙酰肼基团中,N-N键相对较短[1.413 (2) Å],表明分子中存在一定程度的电子离域。在晶体中,分子通过N-H⋯N和N-H⋯O氢键连接成平行于ab平面的片层。