Division of Chemistry, Department of Biochemistry, University of Texas Southwestern Medical Center, Dallas, Texas 75390, USA.
Org Lett. 2012 Jul 6;14(13):3494-7. doi: 10.1021/ol301463c. Epub 2012 Jun 26.
Aryl and heteroaryl boronic acids and boronate esters are rapidly, often within minutes, transformed into the corresponding phenols by N-oxides in an open flask at ambient temperature. This transformation has broad compatibility with a variety of functional groups.
芳基和杂芳基硼酸和硼酸酯在开放烧瓶中、在室温下、通过 N-氧化物迅速(通常在几分钟内)转化为相应的酚。这种转化与各种官能团具有广泛的兼容性。