杂环合成中的偕烃基取代膦-碘鎓盐叶立德。
Hetaryl-substituted phosphonium-iodonium ylides in synthesis of heterocycles.
机构信息
Department of Chemistry, Moscow State Lomonosov University, Russian Federation 119992, Moscow, Lenin Hills 1, Russia.
出版信息
J Org Chem. 2012 Jul 6;77(13):5770-4. doi: 10.1021/jo3008836. Epub 2012 Jun 27.
PMID:22734883
Abstract
A series of hitherto unknown hetaryl-substituted (in phosphonium part) phosphonium-iodonium ylides were synthesized. The reaction of these mixed phosphonium-iodonium ylides with acetylenes opens a way to new furyl annelated phosphinolines or unusually substituted phosphininofurans.
摘要
合成了一系列 hitherto unknown 的杂芳基取代的（膦部分）磷鎓-碘鎓叶立德。这些混合磷鎓-碘鎓叶立德与炔烃的反应为新型呋喃并膦啉或异常取代的磷杂呋喃的合成开辟了道路。
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