化学诱导动态核极化（CIDNP）作为揭示反应机理的工具：混合鏻-碘叶立德与对甲氧基苯乙炔的相互作用

CIDNP as a tool to unveil the reaction mechanism: interaction of mixed phosphonium-iodonium ylide with -methoxyphenylacetylene.

作者信息

Levina Irina I, Tarasov Valery F, Podrugina Tatyana A, Nekipelova Tatiana D

机构信息

Emanuel Institute of Biochemical Physics RAS Kosygin St. 4 Moscow 119334 Russia

Semenov Institute of Chemical Physics RAS Kosygin St. 4 Moscow 119991 Russia.

出版信息

RSC Adv. 2019 Aug 21;9(45):26219-26223. doi: 10.1039/c9ra05697a. eCollection 2019 Aug 19.

acquisition of the reaction between benzoyl phosphonium-iodonium ylide and -methoxyphenylacetylene in an NMR spectrometer reveals the CIDNP effect in P and H NMR spectra of major products, substituted furan (emission) and phosphonium salt (enhanced absorption). The mechanism of products formation radical pairs is discussed.