核壳结构介孔硅：一种用于铑催化不对称转移氢化的新型固定化策略。
Core-shell structured mesoporous silica: a new immobilized strategy for rhodium catalyzed asymmetric transfer hydrogenation.
机构信息
The Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Normal University, Shanghai, China.
出版信息
Chem Commun (Camb). 2012 Aug 14;48(63):7874-6. doi: 10.1039/c2cc33512c. Epub 2012 Jul 3.
PMID:22751461
Abstract
A core-shell structured heterogeneous rhodium catalyst exhibited excellent catalytic activity and enantioselectivity in asymmetric transfer hydrogenation of aromatic ketones in aqueous medium, which could be recovered easily and used repetitively twelve times without affecting obviously its enantioselectivity.
摘要
一种核壳结构的非均相铑催化剂在水相介质中对芳香酮的不对称转移氢化反应表现出优异的催化活性和对映选择性，该催化剂易于回收，可重复使用 12 次而对其对映选择性没有明显影响。
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