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4,6-二氯-2-((E)-{4-[(E)-3,5-二氯-2-羟基-亚苄基氨基]-丁基亚氨基}-甲基)苯酚

4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hy-droxy-benzyl-idene-amino]-butyl-imino}-meth-yl)phenol.

作者信息

Kargar Hadi, Kia Reza, Adabi Ardakani Amir, Tahir Muhammad Nawaz

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2244-5. doi: 10.1107/S1600536812028693. Epub 2012 Jun 30.

Abstract

The asymmetric unit of the title compound, C(18)H(16)Cl(4)N(2)O(2), comprises half of a potentially tetra-dentate Schiff base ligand. It is located about a twofold rotation axis that bis-ects the central C-C bond of the butane-1,4-diamine group. There are two intra-molecular O-H⋯N hydrogen bonds making S(6) ring motifs. In the crystal, mol-ecules are linked by pairs of weak C-H⋯Cl inter-actions, forming inversion dimers, which are further connected by C-H⋯O hydrogen bonds into two-dimensional frameworks that lie parallel to (001).

摘要

标题化合物C(18)H(16)Cl(4)N(2)O(2)的不对称单元包含一个潜在的四齿席夫碱配体的一半。它位于一个二重旋转轴上,该轴平分丁烷-1,4-二胺基团的中心C-C键。存在两个分子内O-H⋯N氢键,形成S(6)环模式。在晶体中,分子通过成对的弱C-H⋯Cl相互作用连接,形成反演二聚体,这些二聚体通过C-H⋯O氢键进一步连接成平行于(001)的二维框架。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f2a2/3394034/a1ed3f48ed3a/e-68-o2244-fig1.jpg

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