• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

N'-[(E)-4-氯-亚苄基]吡啶-4-碳酰肼一水合物

N'-[(E)-4-Chloro-benzyl-idene]pyridine-4-carbohydrazide monohydrate.

作者信息

Fun Hoong-Kun, Loh Wan-Sin, Shetty Divya N, Narayana B, Sarojini B K

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2303-4. doi: 10.1107/S1600536812029121. Epub 2012 Jun 30.

DOI:10.1107/S1600536812029121
PMID:22798943
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3394078/
Abstract

The asymmetric unit of the title compound, C(13)H(10)ClN(3)O·H(2)O, consists of two crystallographically independent Schiff base mol-ecules which exist in an E conformation with respect to the C=N double bond, and two independent water mol-ecules. In the crystal, the Schiff base and water mol-ecules are linked into a three-dimensional network via N-H⋯O, O-H⋯N, O-H⋯O and C-H⋯O hydrogen bonds. The crystal studied was a pseudo-merohedral twin with twin law (101 0-10 00-1) and a component ratio of 0.792 (2):0.208 (2).

摘要

标题化合物C(13)H(10)ClN(3)O·H(2)O的不对称单元由两个晶体学独立的席夫碱分子和两个独立的水分子组成，席夫碱分子相对于C=N双键呈E构型。在晶体中，席夫碱分子和水分子通过N-H⋯O、O-H⋯N、O-H⋯O和C-H⋯O氢键连接成三维网络。所研究的晶体是一个具有(101 0-10 00-1)孪晶律的假准同形孪晶，组分比为0.792 (2):0.208 (2)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e8fe/3394078/47caeaf94b7f/e-68-o2303-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e8fe/3394078/9aa49b63b92b/e-68-o2303-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e8fe/3394078/47caeaf94b7f/e-68-o2303-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e8fe/3394078/9aa49b63b92b/e-68-o2303-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e8fe/3394078/47caeaf94b7f/e-68-o2303-fig2.jpg

相似文献

1
N'-[(E)-4-Chloro-benzyl-idene]pyridine-4-carbohydrazide monohydrate.N'-[(E)-4-氯-亚苄基]吡啶-4-碳酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2303-4. doi: 10.1107/S1600536812029121. Epub 2012 Jun 30.
2
Bis{(E)-N'-[2,4-bis(trifluoro-meth-yl)benzyl-idene]isonicotinohydrazide} monohydrate.双{(E)-N'-[2,4-双(三氟甲基)亚苄基]异烟酰肼}一水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 3;66(Pt 8):o1918-9. doi: 10.1107/S1600536810025493.
3
(E)-N'-[3-(4-Chloro-benzo-yloxy)benzyl-idene]pyridine-4-carbohydrazide acetic acid monosolvate monohydrate.（E）-N'-[3-（4-氯苯氧基）亚苄基]吡啶-4-碳酰肼乙酸单溶剂合物一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1517. doi: 10.1107/S1600536812017369. Epub 2012 Apr 25.
4
(E)-N'-(5-Chloro-2-hydroxy-benzyl-idene)-4-(8-quinol-yloxy)butanohydrazide monohydrate.（E）-N'-（5-氯-2-羟基-亚苄基）-4-（8-喹啉氧基）丁酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):o1695-6. doi: 10.1107/S1600536809023733.
5
3-Chloro-N'-(3-eth-oxy-2-hy-droxy-benzyl-idene)benzohydrazide monohydrate.3-氯-N'-(3-乙氧基-2-羟基亚苄基)苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):o377. doi: 10.1107/S160053681100122X.
6
(E)-N'-(3-Bromo-5-chloro-2-hy-droxy-benzyl-idene)nicotinohydrazide.（E）-N'-（3-溴-5-氯-2-羟基亚苄基）烟酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2716. doi: 10.1107/S1600536811038268. Epub 2011 Sep 30.
7
(E)-N'-(2,4,5-Trimethoxy-benzyl-idene)isonicotinohydrazide dihydrate.（E）-N'-（2,4,5-三甲氧基-亚苄基）异烟酰肼二水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 30;66(Pt 5):o1235-6. doi: 10.1107/S1600536810015254.
8
4-Methyl-benzoic acid-N'-[(E)-4-methyl-benzyl-idene]pyridine-4-carbohydrazide-water (1/1/1).4-甲基苯甲酸-N'-[(E)-4-甲基亚苄基]吡啶-4-碳酰肼-水（1/1/1）
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1492. doi: 10.1107/S1600536812016868. Epub 2012 Apr 21.
9
4-Chloro-N'-(2-hydroxy-benzyl-idene)benzohydrazide monohydrate.4-氯-N'-(2-羟基-亚苄基)苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1694. doi: 10.1107/S1600536808024471.
10
(E)-N'-(4-Chloro-benzyl-idene)-1-benzofuran-2-carbohydrazide monohydrate.（E）-N'-（4-氯-亚苄基）-1-苯并呋喃-2-碳酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2163. doi: 10.1107/S1600536812027523. Epub 2012 Jun 23.

引用本文的文献

1
N'-[(E)-4-Hy-droxy-benzyl-idene]-2-(naph-tha-len-2-yl-oxy)acetohydrazide.N'-[(E)-4-羟基-亚苄基]-2-(萘-2-基氧基)乙酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):o2923-4. doi: 10.1107/S1600536812038408. Epub 2012 Sep 12.

本文引用的文献

1
N'-[(E)-3-Chloro-2-fluoro-benzyl-idene]-6-methyl-nicotinohydrazide monohydrate.N'-[(E)-3-氯-2-氟-亚苄基]-6-甲基烟酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2122. doi: 10.1107/S1600536812026736. Epub 2012 Jun 16.
2
N'-(2,6-Difluoro-benzyl-idene)pyridine-4-carbohydrazide.N'-(2,6-二氟-亚苄基)吡啶-4-碳酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1484. doi: 10.1107/S1600536812016716. Epub 2012 Apr 21.
3
Bis{(E)-N'-[2,4-bis(trifluoro-meth-yl)benzyl-idene]isonicotinohydrazide} monohydrate.
双{(E)-N'-[2,4-双(三氟甲基)亚苄基]异烟酰肼}一水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 3;66(Pt 8):o1918-9. doi: 10.1107/S1600536810025493.
4
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
5
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.