Sow Yaya, Diop Libasse, Kociok-Kohn Gabriele, Molloy Kieran C
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m1015-6. doi: 10.1107/S1600536812028905. Epub 2012 Jun 30.
The title salt, [(CH(3))(2)NH(2)][Sn(C(6)H(5))(3)Cl(2)], was obtained as a by-product of the reaction between bis-(dimethyl-ammonium) oxalate and triphenyl-tin chloride. In the stannate anion, the trigonal-bipyramidal coordination environment of the Sn(IV) atom is defined by the phenyl groups in equatorial and the Cl atoms in axial positions. The cations are connected to adjacent anions through N-H⋯Cl and C-H⋯Cl hydrogen-bonding inter-actions, leading to a chain motif parallel to [100].
标题盐[(CH(3))(2)NH(2)][Sn(C(6)H(5))(3)Cl(2)]是草酸双（二甲铵）与三苯基氯化锡反应的副产物。在锡酸盐阴离子中，Sn(IV)原子的三角双锥配位环境由赤道平面上的苯基和轴向位置的Cl原子确定。阳离子通过N-H⋯Cl和C-H⋯Cl氢键相互作用与相邻阴离子相连，形成平行于[100]的链状结构。
