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二氯三苯基锡（IV）苄基三苯基鏻盐

Benzyl-triphenyl-phospho-nium dichlorido-triphenyl-stannate(IV).

作者信息

Traore Bocar, Boye Mouhamadou Sembene, Sidibe Mamadou, Diop Libasse, Guionneau Philippe

机构信息

Departement de Chimie, Faculté des Sciences et Techniques, Université Cheikh, Anta Diop, Dakar, Senegal.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m42. doi: 10.1107/S1600536812049689. Epub 2012 Dec 12.

DOI:10.1107/S1600536812049689
PMID:23476339
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588253/
Abstract

The crystal structure of the title salt, (C25H22P)[Sn(C6H5)3Cl2] or (PhCH2PPh3)[SnPh3Cl2], consists of PhCH2PPh3 cations and SnPh3Cl2 anions in which the Sn(IV) atom is linked to two Cl atoms and three phenyl groups in a trigonal-bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetra-hedral geometry. In the crystal, the cations and the anions are connected by C-H⋯Cl hydrogen bonds, leading to an infinite chain propagating along the c direction.

摘要

标题盐（C25H22P）[Sn（C6H5）3Cl2] 或（PhCH2PPh3）[SnPh3Cl2] 的晶体结构由 PhCH2PPh3 阳离子和 SnPh3Cl2 阴离子组成，其中 Sn(IV) 原子以三角双锥几何构型与两个 Cl 原子和三个苯基相连，Cl 原子处于反式位置。阳离子呈四面体几何构型。在晶体中，阳离子和阴离子通过 C-H⋯Cl 氢键相连，形成沿 c 轴方向延伸的无限链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0efe/3588253/c793655a7b6a/e-69-00m42-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0efe/3588253/59c33a9489bf/e-69-00m42-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0efe/3588253/c793655a7b6a/e-69-00m42-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0efe/3588253/59c33a9489bf/e-69-00m42-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0efe/3588253/c793655a7b6a/e-69-00m42-fig2.jpg

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