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四乙基铵三（硫氰酸根合-κN）[三（1H-吡唑-1-基-κN(2)）甲烷]镍（II）酸盐

Tetra-ethyl-ammonium tris-(thio-cyanato-κN)[tris-(1H-pyrazol-1-yl-κN(2))methane]-nickelate(II).

作者信息

Lyubartseva Ganna, Parkin Sean, Mallik Uma Prasad, Jeon Hee Kyung

机构信息

Department of Chemistry and Physics, Southern Arkansas University, Magnolia, AR 71753, USA.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m888. doi: 10.1107/S1600536812024774. Epub 2012 Jun 13.

DOI:10.1107/S1600536812024774
PMID:22807731
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3393163/
Abstract

The title salt, (C₈H₂₀N)[Ni(NCS)₃(C₁₀H₁₀N₆)], consists of a tetra-ethyl-ammonium cation and an anion comprising an octa-hedral Ni(II) atom surrounded by three N atoms from a tripodal tris-(pyrazol-1-yl)methane ligand, and three thio-cyanate ligands, each bound at the N-atom end. The ligand Ni-N distances range from 2.097 (2) to 2.127 (2) Å for the tripodal ligand and from 2.045 (2) to 2.075 (2) Å for the thio-cyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°.

摘要

标题盐（C₈H₂₀N）[Ni（NCS）₃（C₁₀H₁₀N₆）]由一个四乙铵阳离子和一个阴离子组成，阴离子包含一个八面体Ni（II）原子，该原子被来自三脚架状三（吡唑-1-基）甲烷配体的三个N原子以及三个硫氰酸酯配体包围，每个硫氰酸酯配体都在N原子端键合。三脚架状配体的配体Ni-N距离范围为2.097（2）至2.127（2）Å，硫氰酸酯配体的配体Ni-N距离范围为2.045（2）至2.075（2）Å。三个吡唑环之间的二面角分别为59.03（12）、53.09（10）和67.90（10）°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e24/3393163/87164ee89dc0/e-68-0m888-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e24/3393163/ad56aaac83d8/e-68-0m888-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e24/3393163/87164ee89dc0/e-68-0m888-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e24/3393163/ad56aaac83d8/e-68-0m888-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e24/3393163/87164ee89dc0/e-68-0m888-fig2.jpg

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