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(乙酸根-κO)(乙酸根-κ²O,O')[2-(3,5-二甲基-1H-吡唑-1-基-κN²)喹啉-κN]锌(II)

(Acetato-κO)(acetato-κ²O,O')[2-(3,5-di-methyl-1H-pyrazol-1-yl-κN²)quinoline-κN]zinc(II).

作者信息

Najib Muhd Hidayat Bin, Tan Ai Ling, Young David J, Ng Seik Weng, Tiekink Edward R T

机构信息

Faculty of Science, Universiti Brunei Darussalam, Jalan Tungku Link BE 1410, Negara Brunei Darussalam.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m897-8. doi: 10.1107/S1600536812025664. Epub 2012 Jun 13.

Abstract

The Zn(II) atom in the title compound, [Zn(C₂H₃O₂)₂(C₁₄H₁₃N₃)], is coordinated by an N₂O₃ donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxyl-ate-O atoms derived from the monodentate and bidentate carboxyl-ate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋯O = 2.858 (2) Å]. In the crystal, mol-ecules are consolidated into a three-dimensional architecture by C-H⋯O inter-actions.

摘要

在标题化合物[Zn(C₂H₃O₂)₂(C₁₄H₁₃N₃)]中,Zn(II)原子由一个由螯合杂环配体的喹啉基和吡唑基-N原子定义的N₂O₃供体集以及来自单齿和双齿羧酸盐配体的三个羧酸盐-O原子配位。与理想的正方锥配位几何结构的偏差与螯合配体受限的咬角有关,即O-Zn-O = 59.65 (5)°和N-Zn-N = 76.50 (6)°,以及非配位羰基原子的近距离接近[Zn⋯O = 2.858 (2) Å]。在晶体中,分子通过C-H⋯O相互作用巩固成三维结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/adc0/3393171/035d9f9a80be/e-68-0m897-fig1.jpg

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