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双[苄基 N'-(3-苯基-2-丙烯叉基)二硫代氨基甲酸根合-κ(2)N',S]汞(II)

Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)dithio-carbazato-κ(2)N',S]mercury(II).

作者信息

Islam M A A A A, Reza M S, Tarafder M T H, Sheikh M C, Zangrando E

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m924-5. doi: 10.1107/S1600536812025901. Epub 2012 Jun 16.

DOI:10.1107/S1600536812025901
PMID:22807758
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3393190/
Abstract

In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra-hedral coordination geometry best described as bis-phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro-gen and the thiol-ate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75 (10)°. In the crystal, weak C-H⋯S inter-actions give rise to chains extending along the c axis.

摘要

在标题化合物[Hg(C₁₇H₁₅N₂S₂)₂]中，Hg(II)离子位于一个晶体学二重旋转轴上，形成了一种非常扭曲的四面体配位几何结构，最好描述为双锥型，由两个去质子化的N,S席夫碱配体通过偶氮甲碱氮原子和硫醇盐硫供体进行螯合。两个螯合配体部分之间的二面角为79.75 (10)°。在晶体中，弱的C-H⋯S相互作用导致沿c轴延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e87/3393190/65417cd813cc/e-68-0m924-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e87/3393190/65417cd813cc/e-68-0m924-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e87/3393190/65417cd813cc/e-68-0m924-fig1.jpg

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