Reza M S, Islam M A A A A, Tarafder M T H, Sheikh M C, Zangrando E
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m976-7. doi: 10.1107/S1600536812028127. Epub 2012 Jun 30.
In the title complex, [Cd(C(17)H(15)N(2)S(2))(2)], the Cd(II) ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bis-phenoidal. The two deprotonated Schiff base ligands chelate the Cd(II) ion through the azomethine N and the thiol-ate S atom. The dihedral angle between the two chelating ligands is 84.01 (9)°. Weak inter-molecular C-H⋯S inter-actions lead to the formation of chains along the c axis.
在标题配合物[Cd(C₁₇H₁₅N₂S₂)₂]中,Cd(II)离子位于二重旋转轴上,在一个严重扭曲的配位环境中呈现出配位数为4的情况,这种环境最好描述为双锥状。两个去质子化的席夫碱配体通过偶氮甲碱N和硫醇盐S原子与Cd(II)离子螯合。两个螯合配体之间的二面角为84.01 (9)°。弱的分子间C—H⋯S相互作用导致沿c轴形成链状结构。