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利用沉积物质量准则和污染指标评估希腊表层海洋和湖泊沉积物中的重金属和多环芳烃污染。

Use of Sediment Quality Guidelines and pollution indicators for the assessment of heavy metal and PAH contamination in Greek surficial sea and lake sediments.

机构信息

Department of Environmental Engineering, Technical University of Crete, Politechnioupolis, Chania, 73100, Greece.

出版信息

Environ Monit Assess. 2013 Mar;185(3):2843-53. doi: 10.1007/s10661-012-2754-2. Epub 2012 Jul 22.

Abstract

Eight different surface sediment samples (K1-K8) were collected from two separate areas of Lake Koumoundourou and two samples (E1 and E2) from one area of Elefsis Bay, Athens, Greece. The level of pollution attributed to heavy metals was evaluated using several pollution indicators. Degree of Contamination, Modified Contamination Degree and Geoaccumulation Indexes were applied in order to determine and assess the anthropogenic contribution of the selected six elements (Cr, Ni, Cu, Zn, As and Pb). Moreover, the adverse effects of the sediments to aquatic organisms, from both heavy metals and polycyclic aromatic hydrocarbons (PAHs), were determined by using Sediment Quality Guidelines. The results indicated that Lake Koumoundourou is contaminated with heavy metals in a moderate degree and almost 50 % of the sediments are associated with frequent observation of adverse effects, when it comes to Ni and occasional observation of adverse effects, when it comes to Cu, Zn and Pb. As far as PAHs are concerned, around 60 % of the samples can be occasionally associated to toxic biological effects according to the effect-range classification for phenanthrene, benzo(a)anthracene, chrysene and pyrene. Finally, samples taken from the north side of the lake are more contaminated with PAHs than the ones taken from the east side probably due to the existence of the water barrier which acts as a reservoir of PAHs.

摘要

从希腊雅典的科蒙都鲁湖(Koumoundourou)的两个不同区域采集了 8 个表层沉积物样本(K1-K8),从雅典的埃莱夫西斯湾(Elefsis Bay)的一个区域采集了 2 个样本(E1 和 E2)。使用多种污染指标评估了归因于重金属的污染程度。应用污染程度指数、修正污染程度指数和地质累积指数来确定和评估所选六种元素(Cr、Ni、Cu、Zn、As 和 Pb)的人为贡献。此外,还使用沉积物质量准则来确定重金属和多环芳烃(PAHs)对水生生物的不利影响。结果表明,科蒙都鲁湖受到重金属中度污染,约 50%的沉积物存在不利影响,其中 Ni 频繁出现,Cu、Zn 和 Pb 偶尔出现不利影响。就 PAHs 而言,根据菲、苯并(a)蒽、荧蒽和芘的效应范围分类,约 60%的样本可能偶尔与有毒生物效应相关。最后,由于存在充当 PAHs 储库的水障,湖的北侧采集的样本比东侧采集的样本更受 PAHs 污染。

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