Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore.
Chem Commun (Camb). 2012 Sep 7;48(69):8709-11. doi: 10.1039/c2cc33641c. Epub 2012 Jul 24.
A highly efficient metal-free intermolecular C(sp3)-C(sp3) allyl-allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.
发展了一种高效的无金属的分子间 C(sp3)-C(sp3)烯丙基-烯丙基交叉偶联反应，该反应在催化三氟甲磺酸根存在下，通过烯丙基乙酸酯和烯丙基三甲基硅烷反应，顺利进行，形成了具有良好至优异区域选择性的 1,5-二烯。
