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从生物质废料到大面积、高质量、掺氮石墨烯：任意基底上壳聚糖涂层的无催化剂碳化。

From biomass wastes to large-area, high-quality, N-doped graphene: catalyst-free carbonization of chitosan coatings on arbitrary substrates.

机构信息

Instituto Universitario de Tecnología Química CSIC-UPV, Univ. Polit. Valencia, 46022-Valencia, Spain.

出版信息

Chem Commun (Camb). 2012 Sep 25;48(74):9254-6. doi: 10.1039/c2cc34978g. Epub 2012 Aug 8.

DOI:10.1039/c2cc34978g
PMID:22875403
Abstract

Chitosan is a N-containing biopolymer that can form high-quality films on glass, quartz, metals and other hydrophilic surfaces. Pyrolysis of chitosan films under argon at 800 °C and under inert atmosphere gives rise to high-quality single layer N-doped graphene films (over 99% transmittance) as evidenced by XPS, Raman spectroscopy, and TEM imaging.

摘要

壳聚糖是一种含氮的生物聚合物，可在玻璃、石英、金属和其他亲水表面形成高质量的薄膜。在氩气和惰性气氛下，壳聚糖薄膜在 800°C 下热解会产生高质量的单层 N 掺杂石墨烯薄膜（透光率超过 99%），这一点可通过 XPS、拉曼光谱和 TEM 成像得到证明。

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