4-羟甲基-10-甲氧基-17,22-二氧杂五环-[21.2.2.2(13,16).1(3,7).0(11,30)]三十碳-1(25),3,5,7(30),8,10,13,15,23,26,28-十一碳烯-2,12-二酮丙酮单溶剂化物
4-Hy-droxy-methyl-10-meth-oxy-17,22-dioxapenta-cyclo-[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca-ene-2,12-dione acetone monosolvate.
作者信息
Hijikata Daichi, Sasagawa Kosuke, Yoshiwaka Sayaka, Okamoto Akiko, Yonezawa Noriyuki
机构信息
Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, Koganei, Tokyo 184-8588, Japan.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2598-9. doi: 10.1107/S1600536812033521. Epub 2012 Jul 28.
In the title compound, C(30)H(26)O(6)·C(3)H(6)O, the syn-oriented benzoyl groups are nearly parallel to each other; the dihedral angle between their benzene rings is 15.9 (1)°. They form dihedral angles of 72.5 (1) and 84.3 (1)° with the naphthalene system. In the crystal, mol-ecules are linked into a three-dimensional architecture by C-H⋯O and C-H⋯π inter-actions.
在标题化合物C(30)H(26)O(6)·C(3)H(6)O中，同向排列的苯甲酰基几乎相互平行；它们苯环之间的二面角为15.9 (1)°。它们与萘环体系形成的二面角分别为72.5 (1)°和84.3 (1)°。在晶体中，分子通过C-H⋯O和C-H⋯π相互作用连接成三维结构。
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