Fun Hoong-Kun, Horkaew Jirapa, Chantrapromma Suchada
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2644-5. doi: 10.1107/S1600536811036579. Epub 2011 Sep 14.
The mol-ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), exists in a trans conformation with respect to the C=N double bond and is twisted, the dihedral angle between the two benzene rings being 24.17 (6)°. The meth-oxy group is almost co-planar with respect to the attached benzene ring [C(m)-O-C-C (m = meth-yl) = -1.45 (17)°]. In the crystal, the mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds into sheets parallel to the bc plane. These sheets are further connected into a three-dimensional network by weak C-H⋯O and C-H⋯π inter-actions.
标题苯甲酰肼衍生物C(15)H(14)N(2)O(4)的分子相对于C=N双键呈反式构象且发生扭曲,两个苯环之间的二面角为24.17 (6)°。甲氧基相对于相连的苯环几乎共平面[C(m)-O-C-C(m = 甲基)=-1.45 (17)°]。在晶体中,分子通过N-H⋯O和O-H⋯O氢键连接成平行于bc平面的片层。这些片层通过弱的C-H⋯O和C-H⋯π相互作用进一步连接成三维网络。