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Synthesis of α-amino acid derivatives and peptides via enantioselective addition of masked acyl cyanides to imines.
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Strategies for the Catalytic Enantioselective Synthesis of -Trifluoromethyl Amines.
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Nickel-catalyzed enantioselective vinylation of aryl 2-azaallyl anions.
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2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines.
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Pd-Catalyzed Allylation of Imines to Access α-CF-Substituted α-Amino Acid Derivatives.
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Intramolecular Umpolung Synthesis of Exocyclic β-Amino Alcohols through Decarboxylative Amination.
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Transition-metal-free chemo- and regioselective vinylation of azaallyls.
Nat Chem. 2017 Oct;9(10):997-1004. doi: 10.1038/nchem.2760. Epub 2017 Apr 17.
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Deciphering the Fluorine Code-The Many Hats Fluorine Wears in a Protein Environment.
Acc Chem Res. 2017 Sep 19;50(9):2093-2103. doi: 10.1021/acs.accounts.7b00226. Epub 2017 Aug 12.
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Umpolung Synthesis of Diarylmethylamines via Palladium-Catalyzed Arylation of -Benzyl Aldimines.
Adv Synth Catal. 2016 Jun 16;358(12):1910-1915. doi: 10.1002/adsc.201600075. Epub 2016 May 12.
5
Catalytic Asymmetric Synthesis of Chiral γ-Amino Ketones via Umpolung Reactions of Imines.
J Am Chem Soc. 2016 Dec 14;138(49):15817-15820. doi: 10.1021/jacs.6b09754. Epub 2016 Nov 30.
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Biologically active γ-lactams: synthesis and natural sources.
Org Biomol Chem. 2016 Nov 2;14(43):10134-10156. doi: 10.1039/c6ob01349j.
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Catalytic Asymmetric Umpolung Allylation of Imines.
J Am Chem Soc. 2016 Oct 12;138(40):13103-13106. doi: 10.1021/jacs.6b05288. Epub 2016 Sep 28.
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Phosphine-Catalyzed Asymmetric Umpolung Addition of Trifluoromethyl Ketimines to Morita-Baylis-Hillman Carbonates.
Angew Chem Int Ed Engl. 2016 Oct 10;55(42):13316-13320. doi: 10.1002/anie.201607918.
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Total Synthesis and Biological Evaluation of Tubulysin Analogues.
J Org Chem. 2016 Nov 4;81(21):10302-10320. doi: 10.1021/acs.joc.6b01314. Epub 2016 Aug 5.
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An Organocatalytic Biomimetic Strategy Paves the Way for the Asymmetric Umpolung of Imines.
Angew Chem Int Ed Engl. 2015 Nov 23;54(48):14228-31. doi: 10.1002/anie.201506872. Epub 2015 Oct 13.

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