在非水介质中将 Sb2S3 沉积到介孔 TiO2 层上的化学前体及其在太阳能电池中的应用。
A chemical precursor for depositing Sb2S3 onto mesoporous TiO2 layers in nonaqueous media and its application to solar cells.
机构信息
Solar Energy Materials Research Group, Division of Advanced Materials, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong, Daejeon 305-600, Republic of Korea.
出版信息
Dalton Trans. 2012 Oct 14;41(38):11569-72. doi: 10.1039/c2dt31348k. Epub 2012 Aug 23.
Deposition of nanocrystalline Sb(2)S(3) onto a mesoporous TiO(2) photoanode is an important process in the fabrication of Sb(2)S(3)-sensitized solar cells. In order to generate oxide-free nanosized Sb(2)S(3), a single-source precursor for the chemical bath deposition of Sb(2)S(3) in nonaqueous media, Sb(III)(thioacetamide)(2)Cl(3), was synthesized and used to produce high-quality Sb(2)S(3) for solar cells.
将纳米晶 Sb(2)S(3)沉积到介孔 TiO(2)光阳极上是制备 Sb(2)S(3)敏化太阳能电池的重要过程。为了生成无氧化物的纳米 Sb(2)S(3)，我们合成了一种 Sb(2)S(3)在非水介质中的化学浴沉积的单源前驱体 Sb(III)(硫代乙酰胺)(2)Cl(3)，并将其用于制备高质量的太阳能电池用 Sb(2)S(3)。
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