通过将疏水性过渡金属催化剂包封在表面交联胶束（SCMs）中制备人工金属酶。
Artificial metalloenzymes via encapsulation of hydrophobic transition-metal catalysts in surface-crosslinked micelles (SCMs).
机构信息
Department of Chemistry, Iowa State University, Ames, Iowa 50011-3111, USA.
出版信息
Chem Commun (Camb). 2012 Oct 14;48(80):9998-10000. doi: 10.1039/c2cc33012a.
PMID:22935642
Abstract
Encapsulation of a hydrophobic rhodium catalyst in crosslinked micelles allowed nonpolar substrates to react in water with unusual selectivity.
摘要
将疏水性铑催化剂包埋在交联胶束中，使得非极性底物在水中以不同寻常的选择性发生反应。
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