通过钯催化脱氢环化合成芴酮衍生物。
Synthesis of fluorenone derivatives through Pd-catalyzed dehydrogenative cyclization.
机构信息
Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871, China.
出版信息
Org Lett. 2012 Sep 21;14(18):4850-3. doi: 10.1021/ol302181z. Epub 2012 Aug 31.
PMID:22938567
Abstract
Palladium-catalyzed dual C-H functionalization of benzophenones to form fluorenones by oxidative dehydrogenative cyclization is reported. This method provides a concise and effective route toward the synthesis of fluorenone derivatives, which shows outstanding functional group compatibility.
摘要
报道了钯催化的二苯甲酮的 C-H 双重官能化反应，通过氧化脱氢环化形成芴酮。该方法为芴酮衍生物的合成提供了一种简洁有效的途径，表现出出色的官能团兼容性。
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