Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Tokyo 113-8656, Japan.
Chem Commun (Camb). 2012 Nov 4;48(85):10481-3. doi: 10.1039/c2cc34980a.
Inspired by the enzymatic ping-pong mechanism, we designed a novel "ping-pong polymerization", which employs allylation and hydroformylation in an iterative and alternating manner. Thus, alternating and regioregular vinyl alcohol-vinyl monomer copolymers possessing multiple hydroxy groups in a periodical manner were successfully synthesized.
受酶促乒乓机制的启发，我们设计了一种新颖的“乒乓聚合”，它采用烯丙基化和氢甲酰化的交替和迭代方式。因此，成功地合成了交替且区域规整的乙烯醇-乙烯单体共聚物，这些共聚物在一个周期内具有多个羟基。
