新型高水溶性二酮衍生的碘𬭩叶立德：制备、X 射线结构及与碳二亚胺反应生成噁唑衍生物。
New highly soluble dimedone-derived iodonium ylides: preparation, X-ray structure, and reaction with carbodiimide leading to oxazole derivatives.
机构信息
Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, USA.
出版信息
Chem Commun (Camb). 2012 Oct 18;48(81):10108-10. doi: 10.1039/c2cc35708a.
PMID:22955183
Abstract
Highly soluble dimedone-derived o-alkoxyphenyliodonium ylides have been prepared and characterized by single crystal X-ray diffraction. These new iodonium ylides are useful reagents for the preparation of oxazole derivatives by reaction with carbodiimides.
摘要
高溶解性二甲基酮衍生的邻烷氧基苯碘𬭩叶立德已通过单晶 X 射线衍射进行了制备和表征。这些新型碘𬭩叶立德是通过与碳二亚胺反应制备恶唑衍生物的有用试剂。
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