Lee Young-Jun, Lim Byung-Wook, Kim Joo-Hyung, Kim Tae-Won, Oh Byeong-Yun, Heo Gi-Seok, Kim Kwang-Young
Laboratory of Nano-Micro Devices, Department of Electronic Engineering, Chosun University, Gwangju, 501-759, Korea.
J Nanosci Nanotechnol. 2012 Jul;12(7):5604-8. doi: 10.1166/jnn.2012.6296.
Annealing effect on structural and electrical properties of W-doped IZO (WIZO) films for thin film transistors (TFT) was studied under different process conditions. Thin WIZO films were deposited on glass substrates by RF magnetron co-sputtering technique using indium zinc oxide (10 wt.% ZnO-doped In2O3) and WO3 targets in room temperature. The post annealing temperature was executed from 200 degrees C to 500 degrees C under various O2/Ar ratios. We could not find any big difference from the surface observation of as grown films while it was found that the carrier density and sheet resistance of WIZO films were controlled by O2/Ar ratio and post annealing temperature. Furthermore, the crystallinity of WIZO film was changed as annealing temperature increased, resulting in amorphous structure at the annealing temperature of 200 degrees C, while clear In2O3 peak was observed for the annealed over 300 degrees C. The transmittance of as-grown films over 89% in visible range was obtained. As an active channel layer for TFT, it was found that the variation of resistivity, carrier density and mobility concentration of WIZO film decreased by annealing process.
研究了不同工艺条件下退火对用于薄膜晶体管(TFT)的W掺杂IZO(WIZO)薄膜的结构和电学性能的影响。采用射频磁控共溅射技术,在室温下使用氧化铟锌(10 wt.% ZnO掺杂的In2O3)靶材和WO3靶材,在玻璃基板上沉积了WIZO薄膜。在不同的O2/Ar比下,将退火温度从200℃提高到500℃。从生长态薄膜的表面观察中未发现任何显著差异,但发现WIZO薄膜的载流子密度和薄层电阻受O2/Ar比和退火温度的控制。此外,随着退火温度的升高,WIZO薄膜的结晶度发生变化,在200℃退火温度下为非晶结构,而在300℃以上退火时观察到清晰的In2O3峰。生长态薄膜在可见光范围内的透过率超过89%。作为TFT的有源沟道层,发现通过退火工艺,WIZO薄膜的电阻率、载流子密度和迁移率浓度的变化减小。