• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2,2'-[(1E,2E)-1,2-双(羟基亚氨基)-乙烷-1,2-二亚基]二吡啶鎓六氯铼(IV)酸盐

2,2'-[(1E,2E)-1,2-Bis(hy-droxy-imino)-ethane-1,2-di-yl]dipyridinium hexa-chloridorhenate(IV).

作者信息

Krawczyk Monika K, Krawczyk Marta S, Siczek Miłosz, Lis Tadeusz

机构信息

University of Wrocław, Faculty of Chemistry, 14 Joliot-Curie St, 50-383 Wrocław, Poland.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1174-5. doi: 10.1107/S1600536812035052. Epub 2012 Aug 15.

DOI:10.1107/S1600536812035052
PMID:22969470
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435597/
Abstract

The title salt, (C(12)H(12)N(4)O(2))[ReCl(6)], consists of 2,2'-[(1E,2E)-1,2-bis-(hy-droxy-imino)-ethane-1,2-di-yl]dipyridinium cations and ReCl(6) anions which are both located on inversion centres. Each cation consists of a glyoxime moiety attached to two protonated pyridine rings in ortho positions. In the crystal, E,E isomers of the cation are observed which differ in the spatial arrangement of the pyridine rings. These rings are positionally disordered over two positions with site-occupancy factors of 0.786 (7) and 0.214 (7). The geometry of the cation is compared with that of a recently reported dipyridyl-glyoxime with the same configuration. The cations and anions are involved in a network of inter-molecular O-H⋯Cl, N-H⋯Cl and C-H⋯Cl hydrogen bonds.

摘要

标题盐（C(12)H(12)N(4)O(2))[ReCl(6)]由2,2'-[(1E,2E)-1,2-双-(羟基-亚氨基)-乙烷-1,2-二亚基]二吡啶鎓阳离子和[ReCl(6)]²⁻阴离子组成，二者均位于对称中心上。每个阳离子由一个连有两个处于邻位的质子化吡啶环的乙二肟部分组成。在晶体中，观察到阳离子的E,E异构体，其吡啶环的空间排列不同。这些环在两个位置上位置无序，占位因子分别为0.786 (7)和0.214 (7)。将该阳离子的几何结构与最近报道的具有相同构型的二吡啶基乙二肟的几何结构进行了比较。阳离子和阴离子通过分子间O-H⋯Cl、N-H⋯Cl和C-H⋯Cl氢键形成网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa25/3435597/db1ff956b5f9/e-68-m1174-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa25/3435597/38bf85868d47/e-68-m1174-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa25/3435597/0af4719adb13/e-68-m1174-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa25/3435597/992c92225715/e-68-m1174-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa25/3435597/db1ff956b5f9/e-68-m1174-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa25/3435597/38bf85868d47/e-68-m1174-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa25/3435597/0af4719adb13/e-68-m1174-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa25/3435597/992c92225715/e-68-m1174-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa25/3435597/db1ff956b5f9/e-68-m1174-fig4.jpg

相似文献

1
2,2'-[(1E,2E)-1,2-Bis(hy-droxy-imino)-ethane-1,2-di-yl]dipyridinium hexa-chloridorhenate(IV).2,2'-[(1E,2E)-1,2-双(羟基亚氨基)-乙烷-1,2-二亚基]二吡啶鎓六氯铼(IV)酸盐
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1174-5. doi: 10.1107/S1600536812035052. Epub 2012 Aug 15.
2
Bis[(1RS,2RS)-4,4'-(1-aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium] tris-[tetra-chloridopalladate(II)].双[(1RS,2RS)-4,4'-(1-氮杂鎓-2-羟基乙烷-1,2-二亚基)二吡啶鎓]三[四氯钯酸(II)]
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m65-6. doi: 10.1107/S1600536812050817. Epub 2012 Dec 22.
3
(1RS,2RS)-4,4'-(1-Aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium tetra-chlorido-platinate(II) chloride.（1RS，2RS）-4,4'-（1-氮杂鎓基-2-羟基乙烷-1,2-二亚基）二吡啶四氯合铂（II）氯化物
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):m157-8. doi: 10.1107/S160053681300425X. Epub 2013 Feb 20.
4
4,4'-(Ethane-1,2-diyl)dipyridinium bis-(2-hy-droxy-benzoate).4,4'-（乙烷-1,2-二基）二吡啶鎓双（2-羟基苯甲酸酯）
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 2;66(Pt 11):o2701. doi: 10.1107/S160053681003816X.
5
4-[(E)-(Hy-droxy-imino)-meth-yl]-N,N-di-methyl-anilinium chloride.4-[(E)-(羟基亚氨基)-甲基]-N,N-二甲基苯胺氯化物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1705. doi: 10.1107/S1600536812020211. Epub 2012 May 12.
6
Bis(3-hy-droxy-methyl-anilinium) hexa-chloridostannate(IV).六氯锡（IV）酸双（3-羟甲基苯胺鎓）
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m395. doi: 10.1107/S1600536811007252. Epub 2011 Mar 2.
7
2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb-oxy-4-hy-droxy-pyridine-2-carboxyl-ato-κO,N,O)(4-hy-droxy-pyridine-2,6-dicarboxyl-ato-κO,N,O)nickelate(II) 2.35-hydrate: a proton-transfer compound.2,9 - 二甲基 - 1,10 - 菲啰啉鎓（6 - 羧基 - 4 - 羟基 - 吡啶 - 2 - 羧酸根 - κO,N,O）（4 - 羟基 - 吡啶 - 2,6 - 二羧酸根 - κO,N,O）镍酸盐（II）2.35水合物：一种质子转移化合物。
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 11;66(Pt 9):m1084-5. doi: 10.1107/S1600536810031399.
8
(2-Hy-droxy-eth-yl)triphenyl-phospho-nium chloride.（2-羟基乙基）三苯基氯化鏻
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 16;67(Pt 3):o641. doi: 10.1107/S160053681100482X.
9
Bis{2-[3-(hy-droxy-imino-κN)butan-2-yl-idene]-N-methyl-hydrazinecarbothio-amide-κN,S}nickel(II) dichloride.二氯双{2-[3-(羟基亚氨基-κN)丁-2-亚基]-N-甲基肼甲硫酰胺-κN,S}镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m108-9. doi: 10.1107/S1600536811055395. Epub 2012 Jan 7.
10
catena-Poly[(E)-4,4'-(ethane-1,2-di-yl)dipyridinium [[bis-(thio-cyanato-κN)ferrate(II)]-di-μ-thio-cyanato-κN:S;κS:N]].链状聚[（E）-4,4'-（乙烷-1,2-二基）二吡啶鎓[[双（硫氰酸根-κN）铁（II）]-二-μ-硫氰酸根-κN:S;κS:N]]
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1503. doi: 10.1107/S1600536811039924. Epub 2011 Oct 8.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.