{2 - [(2 - 氨基甲酰肼 - 1 - 亚基)甲基 - κ(2)N(1),O] - 5 - 甲氧基 - 苯酚根合 - κO(1)}氯化铜(II)
{2-[(2-Carbamoylhydrazin-1-yl-idene)methyl-κ(2)N(1),O]-5-meth-oxy-phenolato-κO(1)}chloridocopper(II).
作者信息
Kunnath Roji J, Prathapachandra Kurup M R, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1194. doi: 10.1107/S160053681203574X. Epub 2012 Aug 23.
The asymmetric unit of the title compound, [Cu(C(9)H(10)N(3)O(3))Cl], contains two independent mol-ecules with similar structures. The Cu(II) cation is N,O,O'-chelated by the deprotonated Schiff base ligand and is further coordinated by a Cl(-) anion in a distorted ClNO(2) square-planar geometry. In the crystal, adjacent mol-ecules are linked by N-H⋯O and N-H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to [100].
标题化合物[Cu(C₉H₁₀N₃O₃)Cl]的不对称单元包含两个结构相似的独立分子。Cu(II)阳离子由去质子化的席夫碱配体进行N,O,O'-螯合，并进一步由一个Cl⁻阴离子以扭曲的ClNO₂平面正方形几何构型配位。在晶体中，相邻分子通过N—H⋯O和N—H⋯Cl氢键相连，形成一个平行于[100]的二维网络。
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