三水合（2,2'-联吡啶-κ(2)N,N'）{N-[(2-氧代萘-1-基-κO)亚甲基]-L-缬氨酸根-κO}铜(II)
(2,2'-Bipyridine-κ(2)N,N'){N-[(2-oxidonaphthalen-1-yl-κO)methyl-idene]-l-valinato-κO}copper(II) trihydrate.
作者信息
Zuo Jian, Bi Caifeng, Fan Yuhua, Zhang Nan, Zhang Pengfei
机构信息
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong 266100, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m792. doi: 10.1107/S1600536812022702. Epub 2012 May 26.
In the title complex, [Cu(C(16)H(15)NO(3))(C(10)H(8)N(2))]·3H(2)O, the Cu(II) atom is five coordinated by O,N,O'-donor atoms of the Schiff base ligand and by two N atoms of the 2,2'-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal, mol-ecules are linked into a two-dimensional network parallel to (011) by O-H⋯O hydrogen bonds.
在标题配合物[Cu(C₁₆H₁₅NO₃)(C₁₀H₈N₂)]·3H₂O中，Cu(II)原子由席夫碱配体的O、N、O'供体原子以及2,2'-联吡啶配体的两个N原子以扭曲的四方锥几何构型进行五配位。在晶体中，分子通过O—H⋯O氢键连接成平行于(011)的二维网络。
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