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三羰基[三(1-甲基-1H-咪唑-2-基-κN(3))甲醇]三氟甲磺酸锰(I)

Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN(3))methanol]manganese(I) trifluoromethanesulfonate.

作者信息

Reiss Guido J, Kunz Peter C

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1202-3. doi: 10.1107/S1600536812035891. Epub 2012 Aug 23.

DOI:10.1107/S1600536812035891
PMID:22969490
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435617/
Abstract

In the title compound, Mn(C(13)H(16)N(6)O)(CO)(3), the Mn(I) atom has a slightly distorted octa-hedral geometry. The three CO ligands have C-Mn-C angles in the range 89.44 (10)-92.31 (9)°, while the three N atoms of the tripodal ligand form significantly smaller N-Mn-N angles of 82.76 (2)-85.51 (6)°. The three N atoms of the tripodal ligand and the three carbonyl ligands coordinate facially. In the crystal, the trifluoro-methane-sulfonate counter anion is connected by a medium-strength O-H⋯O hydrogen bond to the hydroxyl group of the manganese complex.

摘要

在标题化合物Mn(C₁₃H₁₆N₆O)(CO)₃中，Mn(I)原子具有略微扭曲的八面体几何构型。三个CO配体的C-Mn-C角在89.44 (10)-92.31 (9)°范围内，而三脚架配体的三个N原子形成的N-Mn-N角明显更小，为82.76 (2)-85.51 (6)°。三脚架配体的三个N原子和三个羰基配体以面式配位。在晶体中，三氟甲磺酸盐抗衡阴离子通过中等强度的O-H⋯O氢键与锰配合物的羟基相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/3435617/a889dbafb700/e-68-m1202-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/3435617/a889dbafb700/e-68-m1202-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/3435617/a889dbafb700/e-68-m1202-fig1.jpg

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本文引用的文献

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