三氯[4-甲氧基-2,6-双-(2-嘧啶-2-基-κN)苯基-κC(1)]铂(IV)乙腈单溶剂合物
Trichlorido[4-meth-oxy-2,6-bis-(2-pyrimidin-2-yl-κN)phenyl-κC(1)]platinum(IV) acetonitrile monosolvate.
作者信息
Wu Yang, Xie Dahai, Zhang Dengqing, Li Xianying, Jin Wusong
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1210-1. doi: 10.1107/S1600536812036410. Epub 2012 Aug 25.
In the title complex, [Pt(C(15)H(11)N(4)O)Cl(3)]·CH(3)CN, the Pt(IV) ion adopts a distorted octa-hedral coordination geometry defined by a tridentate cyclo-metalated NCN ligand and three Cl atoms. In the crystal, individual mol-ecules are aggregated into a three-dimensional network by C-H⋯Cl hydrogen-bonding inter-actions and π-π stacking inter-actions between the tridentate ligands, the shortest ring centroid-centroid distance being 3.613 Å.
在标题配合物[Pt(C₁₅H₁₁N₄O)Cl₃]·CH₃CN中，Pt(IV)离子采用由三齿环金属化NCN配体和三个Cl原子定义的扭曲八面体配位几何结构。在晶体中，单个分子通过C—H⋯Cl氢键相互作用和三齿配体之间的π-π堆积相互作用聚集形成三维网络，最短的环心-环心距离为3.613 Å。
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