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双[N-苄基-N-(2-苯基乙基)二硫代氨基甲酸酯-κ(2)S,S']铅(II)

Bis[N-benzyl-N-(2-phenyl-eth-yl)dithio-carbamato-κ(2)S,S']lead(II).

作者信息

Sathiyaraj E, Thirumaran S, Selvanayagam S

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1217. doi: 10.1107/S1600536812036161. Epub 2012 Aug 25.

DOI:10.1107/S1600536812036161
PMID:22969499
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435626/
Abstract

The mol-ecule of the title compound, [Pb(C(16)H(16)NS(2))(2)], is located on a twofold rotation axis, which runs through the Pb(II) atom. The two dithio-carbamate ligands coordinate the metal in a pyramidal configuration through the S atoms. The two phenyl rings of each dithocarbamate ligand are aligned at a dihedral angle of 78.4 (1)°. The mol-ecular conformation is stabilized by intra-molecular C-H⋯S inter-actions.

摘要

标题化合物[Pb(C₁₆H₁₆NS₂)₂]的分子位于一个二重旋转轴上，该轴穿过Pb(II)原子。两个二硫代氨基甲酸盐配体通过硫原子以金字塔形构型与金属配位。每个二硫代氨基甲酸盐配体的两个苯环以78.4 (1)°的二面角排列。分子构象通过分子内C—H⋯S相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a47b/3435626/ba429aa8c904/e-68-m1217-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a47b/3435626/348122fa37d0/e-68-m1217-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a47b/3435626/ba429aa8c904/e-68-m1217-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a47b/3435626/348122fa37d0/e-68-m1217-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a47b/3435626/ba429aa8c904/e-68-m1217-fig2.jpg

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