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N-(2-苯甲酰基-乙基)-2-丙铵氯化物

N-(2-Benzoyl-eth-yl)propan-2-aminium chloride.

作者信息

Aydın Abdullah, Akkurt Mehmet, Gul Halise Inci, Mete Ebru, Sahin Ertan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2702-3. doi: 10.1107/S1600536812035106. Epub 2012 Aug 11.

DOI:10.1107/S1600536812035106
PMID:22969592
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435721/
Abstract

In the title salt, C(12)H(18)NO(+)·Cl(-), N-H⋯Cl inter-actions between the free chloride anions and the organic cations connect the mol-ecules into hydrogen-bond dimers, forming a R(2) (2)(8) motif. The dimers are linked by C-H⋯O hydrogen bonds into chains extending along [301]. The carbonyl group is co-planar with the phenyl ring [C-C-C=O torsion angle = -3.3 (7)°]. The side chain has an E conformation.

摘要

在标题盐C(12)H(18)NO(+)·Cl(-)中,游离氯离子阴离子与有机阳离子之间的N-H⋯Cl相互作用将分子连接成氢键二聚体,形成R(2) (2)(8) motif。这些二聚体通过C-H⋯O氢键连接成沿[301]方向延伸的链。羰基与苯环共平面[C-C-C=O扭转角 = -3.3 (7)°]。侧链具有E构象。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5020/3435721/b57fa9ff6274/e-68-o2702-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5020/3435721/384652f91de3/e-68-o2702-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5020/3435721/b57fa9ff6274/e-68-o2702-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5020/3435721/384652f91de3/e-68-o2702-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5020/3435721/b57fa9ff6274/e-68-o2702-fig2.jpg

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