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N'-[(E)-2-羟基-5-碘苄叉基]-4-甲基苯磺酰肼

N'-[(E)-2-Hy-droxy-5-iodo-benzyl-idene]-4-methyl-benzene-sulfono-hydrazide.

作者信息

Ghorbanloo Massomeh, Notash Behrouz

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2760. doi: 10.1107/S1600536812035738. Epub 2012 Aug 23.

DOI:10.1107/S1600536812035738
PMID:22969641
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435795/
Abstract

In the title mol-ecule, C(14)H(13)IN(2)O(3)S, the dihedral angle between the planes of the benzene and toluene rings is 84.3 (3)°. The mol-ecule displays a trans conformation with respect to the C=N bond. There is an intra-molecular O-H⋯N hydrogen bond with the azomethine N atom as acceptor. In the crystal, N-H⋯O hydrogen bonds connect the mol-ecules into chains running along the b axis.

摘要

在标题分子C₁₄H₁₃IN₂O₃S中，苯环和甲苯环平面之间的二面角为84.3（3）°。该分子相对于C=N键呈反式构象。存在一个分子内O-H⋯N氢键，以偶氮甲碱N原子作为受体。在晶体中，N-H⋯O氢键将分子连接成沿b轴延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f82/3435795/c7b995f7e9b5/e-68-o2760-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f82/3435795/54b7dc76268a/e-68-o2760-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f82/3435795/c7b995f7e9b5/e-68-o2760-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f82/3435795/54b7dc76268a/e-68-o2760-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f82/3435795/c7b995f7e9b5/e-68-o2760-fig2.jpg

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